内容推荐 《Chemical Engineering Thermodynamics》(化工热力学)共8章,第1章介绍了化工热力学的用途、研究内容、研究特点和基本定律;第2章交代了纯物质的相态变化、纯物质的p-V-T关系、气体的状态方程和对比态原理及其应用;第3章详细讨论了热力学性质间的关系和热力学性质的计算;第4章介绍了剩余性质的定义,阐述了多组分混合物的热力学、混合物的实际热力学行为,不同二元混合物的混合摩尔体积、偏摩尔吉布斯能、偏摩尔体积和焓的实验测定,从实验数据计算无限稀释部分摩尔焓、混合物中组分的吉布斯能和逸度的估计以及偏摩尔吉布斯能和逸度;第5章全面介绍了相平衡判据的数学表达式、化学势和逸度及其在相平衡建模中的应用,讲述了测定液体和固体逸度、分布系数、相对挥发性以及热力学一致性检验。第5章主要涉及了相平衡的相关定律和方程;第6章解释了热机的不可逆性的比率、系统的?变化、?在压缩过程中发生变化、?递减原理与?破坏以及?衡算及?效率;第7章介绍了用简单模型分析制冷循环以及卡诺循环和它在工程中的价值,并对蒸汽和联合动力循环、卡诺蒸汽循环、制冷循环和热泵系统进行了相应的解释;第8章讨论了化学反应平衡基础、化学反应的平衡准则、平衡常数和工艺参数等条件对化学平衡组成的影响。 《Chemical Engineering Thermodynamics》注重理论原理与实际应用的结合,不仅能够为读者提供丰富的热力学基础知识,还能为经验丰富的化工工程师提供所需的专业知识。本书附有大量的例题,并且都系统地给出了解答步骤。读者能够通过本书迅速获取化工热力学的知识内容,适合自学,同时也是学习和掌握专业英语的高效途径。 《Chemical Engineering Thermodynamics》(化工热力学)可作为化工及相关专业的本科生和研究生学习化工热力学的教材,也可供化工专业的过程开发、合成、优化等领域的科研人员参考。 目录 Chapter 1 Introduction 1.1 The Category of Chemical Engineering Thermodynamics 1.2 The Role of Thermodynamics in Chemical Engineering 1.3 Fundamental Law of Thermodynamics 1.4 Application of Chemical Engineering Thermodynamics 1.5 The State and System Chapter 2 The Physical Properties of Pure Substances 2.1 Pure Substance 2.2 Phases of Pure Substance 2.3 Phase-change Processes of Pure Substances 2.4 Property Diagrams for Phase-Change Processes 2.4.1 The T-V Diagram 2.4.2 The p-V Diagram 2.4.3 The p-T Diagram 2.4.4 The p-V-T Surface 2.5 Equation of State 2.5.1 The Ideal-Gas Equation of State 2.5.2 Nonideality of Gases 2.6 Other Equations of State 2.6.1 The van der Waals Equation of State 2.6.2 Redlich-Kwong (RK) Equation of State 2.6.3 The Soave-Redlich-Kwong (SRK) Equation of State 2.6.4 Peng-Robinson (PR) Equation of State 2.6.5 Virial Equation of State 2.6.6 Multiparameter Equation of State 2.7 Principle of Corresponding States and Generalized Association 2.7.1 Principle of Corresponding States 2.7.2 Principle of Corresponding States with Two Parameters 2.7.3 Principle of Corresponding States with Three Parameters 2.7.4 Generalized Compressibility Factor Graph Method 2.7.5 Generalized Virial Coefficient Method 2.8 Application of Aspen Plus in Calculation of Thermodynamic Equation of State EXERCISES REFERENCES Chapter 3 Thermodynamic Properties of Pure Fluids 3.1 Mathematical Relationship between Functions 3.1.1 Partial Differentials 3.1.2 Partial Differential Relations 3.1.3 Fundamental Thermodynamic Relation 3.2 The Maxwell Relations 3.3 The Clapeyron Equation 3.4 General Relations for dU, dH, dA, and dG 3.5 Joule-Thomson Coefficient 3.6 The ?H, ?U, and ?S of Real Gas 3.7 Application of Aspen in Thermodynamic Properties CONCLUSION EXERCISES REFERENCES Chapter 4 The Thermodynamics of Multicomponent Mixtures 4.1 Excess Property 4.2 Properties Change on Mixing 4.3 Partial Molar Gibbs Free Energy 4.4 Gibbs-Duhem Equation 4.5 The Experimental Measurement of Partial Molar Volume and Enthalpy 4.6 Gibbs Free Energy and Fugacity of a Component in a Mixture 4.6.1 Ideal Gas Mixture 4.6.2 Ideal Mixture and Excess Mixture Properties 4.6.3 Partial Molar Gibbs Free Energy and Fugacity 4.7 Application of Aspen Plus to Thermodynamic Properties of multicomponent Mixtures CONCLUSION EXERCISES REFERENCES Chapter 5 Phase Equilibrium 5.1 Phase Equilibrium for a Single-Component System 5.1.1 Mathematical Models of Phase Equilibrium 5.1.2 Fugacity and Its Use in Modeling Phase Equilibrium 5.2 Vapor-Liquid Equilibrium 5.2.1 Motivational Example 5.2.2 Raoult's Law and the Presentation of Data 5.2.3 Mixture Critical Points 5.2.4 Lever Rule and the Flash Problem 5.3 Theory and Model of Vapor Liquid Equilibrium of Mixtures: Modified Raoult's law Method 5.3.1 Examples of Incentives 5.3.2 Phase Equilibrium of Mixture 5.3.3 Fugacity of Mixture 5.3.4 Gamma-Phi Modeling 5.3.5 Raoult's law Revisited 5.3.6 Henry's law 5.4 Wilson and Van Laar Equation 5.4.1 Wilson Equation 5.4.2 Relationship between Activity Coefficient and Temperature and Pressure 5.4.3 Van Laar Equation and Regular Solution Theory 5.4.4 Van Der Waals One-Fluid Mixing Rules 5.5 Supplementary Simulation Examples 5.5.1 Vapor-Liquid Equilibrium Calculations Using Activity Coefficient Models 5.5.2 Vapor-Liquid Equilibrium Calculations Using an Equation of State 5.5.3 Prediction of Liquid-Liquid and Vapor-Liquid-Liquid Equilibrium EXERCISES REFERENCES Chapter 6 Energy Analysis of Chemical Process 6.1 The Definition of Entropy Exergy 6.2 Exergy (Work Potential) Associated wit |