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内容推荐 《物理化学(英文版)Physical Chemistry》为“十三五”江苏省高等学校本科重点教材(新编)。本书是在继承既有物理化学中文、英文教材体系成果的基础上编写而成的,在“新工科”理念指导下,注重借助数学、物理等基础科学的理论原理及新实验技术手段研究化学变化中的基本规律。本书共包括九章内容,分别是气体的性质、热力学第一定律、热力学第二定律、多组分系统热力学、化学平衡、相平衡、电化学平衡、化学动力学和界面化学,每章均配有与章节基本概念、公式和知识内容相对应的不同难度的例题、练习题和思考题,有助于巩固掌握基础知识,增强解题及逻辑思维能力。 本书注重提高学生的学习兴趣和效果,培养多学科基础厚实、工程能力强、综合素质高且能实现跨界整合的复合型人才。本书既可作为高等院校化工类、化学类、材料类、生工制药类、环境类等专业基础物理化学课程的全英文教学用书,也可供其他相关专业使用,并可作为相关科研和工程技术人员的参考用书。 目录 Chapter 1 The Properties of Gases 1.1 State Equation of the Ideal Gas 1.1.1 Empirical Laws of Gases 1.1.2 State Equation of Ideal Gas 1.1.3 Model and Definition of Ideal Gas 1.2 The Properties of Mixtures of the Ideal Gases 1.2.1 Composition of Mixtures 1.2.2 Dalton's Law of Partial Pressures 1.2.3 Amagat's Law of Partial Volumes 1.3 State Equations of Real Gas 1.3.1 The van der Waals Equation 1.3.2 Generalized Equation of State for Real Gases 1.4 Isothermal Curves and Liquefaction of Real Gas 1.4.1 Saturated Vapor Pressure of the Liquid 1.4.2 Isothermal Curves and Liquefaction 1.4.3 Critical Parameters and Critical Compression Factor Zc 1.5 Exercises Chapter 2 The First Law of Thermodynamics 2.1 Basic Concepts 2.1.1 System and Surroundings 2.1.2 Property, State, and State Function 2.1.3 Process and Route 2.1.4 Work, Heat, and Energy 2.2 The First Law of Thermodynamics 2.2.1 The First Law of Thermodynamics 2.2.2 Internal Energy 2.3 Heat, Enthalpy, and Heat Capacities 2.3.1 Heat in Isochoric Conditions, and Internal Energy 2.3.2 Heat in Isobaric Conditions, and Enthalpy 2.3.3 Hess's Law 2.3.4 Heat Capacities 2.4 Pressure-Volume Work and Reversible Processes 2.4.1 Pressure-Volume Work 2.4.2 Reversible Processes 2.5 Isoenthalpic Processes 2.5.1 The Joule-Thomson Effect 2.5.2 Adiabatic Joule-Thomson Coefficient 2.6 Thermochemistry 2.6.1 Standard Enthalpy of Formation 2.6.2 Enthalpy of Reaction 2.6.3 Temperature-Dependence of Standard Enthalpy of Reaction 2.7 Exercises Chapter 3 The Second Law of Thermodynamics 3.1 Statements of the Second Law of Thermodynamics 3.1.1 Spontaneous Process 3.1.2 Conversion of Heat and Work 3.1.3 Statements of the Second Law of Thermodynamics 3.2 CarDt Cycle and CarDt Theorem 3.2.1 CarDt Cycle 3.2.2 CarDt Theorem 3.3 Entropy and Clausius Inequality 3.3.1 Derivation and Definition of Entropy 3.3.2 The Clausius Inequality 3.3.3 The Principle of the Increase of Entropy 3.3.4 Physical Significance of Entropy 3.4 The Calculation of Entropy Changes 3.4.1 The Calculation of Entropy Changes in Simple pVT Process 3.4.2 The Calculation of Entropy Changes for Phase Changes 3.5 The Standard Molar Reaction Entropy Change of Chemical Reaction 3.5.1 The Third Law of Thermodynamics 3.5.2 Absolute Entropy and Standard Molar Entropy of Matter 3.5.3 Calculation of Entropy Changes for Chemical Reactions 3.6 The Gibbs and Helmholtz Functions 3.6.1 Helmholtz Function …… Chapter 4 The Thermodynamics of Multi-Component Systems Chapter 5 Chemical Equilibrium Chapter 6 Phase Equilibrium Chapter 7 Electrochemistry Chapter 8 Chemical Kinetics Chapter 9 Interface Chemistry Appendix Reference |