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书名 表面物理学概念(第2版)
分类 科学技术-自然科学-物理
作者 (法)德容凯尔
出版社 世界图书出版公司
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简介
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《表面物理学概念(第2版)》是晶体表面物理学概念和现象的入门书籍。内容涵盖洁净表面和吸附物覆盖表面、原子结构、振动性质、电子结构的热动力学和统计性质以及物理吸附和化学吸附理论。这是第二版,对原有内容的做了较大改动,增加了不少习题,可以引起读者对本学科更大兴趣,更好地投入到这门学问。本书由德容凯尔著。

目录

l. Introduction

2. Thermodynamicil and Statistical Properties of Clean Surfaces

2.1 Thermodynamics of a Surface_at Equilibrium

2.2 Equilibrium Shape of a Crystal

2.3 Facetting

2.4 The Roughening Transition

2.4.1 Generalities

2.4.2 Macroscopic Approach: The Continuum Limit

a)One Dimensional Case:Statistics of a Step

b)The Two Dimensional Case: Statistics of a Surface

2.4.3 Microscopic Approach

a)Equilibrium Shape of a Step Edge

b)Equilibrium Shape of a Surface:

The Roughening Transition

2.4.4 Consequences of the Roughening Transition for the Equilibrium Shape of Crystals and for Crystal Growth

2.4.5 Experimental Evidences of the Roughening Transition

2.4.6 Special Cases of Vicinal Surfaces

Problems

3. Atomic Structure of Surfaces

3.1 Surface Crystallography

3.1.1 Two-Dimensional Lattices

3.1.2 Semi-Infinite Crystals. Relaxation. Reconstruction

3.1.3 Notations for Surface Structures

3.1.4 Vicinal Surfaces

3.1.5 Reciprocal Lattice and Brillouin Zones

3.2 Experimental Techniques

3.2.1 Observation of the Real Lattice

a)Field-ion Microscopy (FIM)

b)Scanning Tunneling Microscopy (STM)

3.2.2 Observation of the Reciprocal Lattice

a)Principles of Diffraction

b)Low Energy Electron Diffraction (LEED)

c)Atom Scattering

d)X-ray Scattering at Grazing Incidence

3.2.3 Indirect Methods

a)Photoelectron Diffraction (PhD)

b)Surface Extended X-ray Absorption Fine Structure (SEXAFS)

c)Other Methods

Problems

4. Vibrations at Surfaces

4.1 Elastic Forces in Crystals

4.1.1 Dynamical Matrix

4.1.2 Interatomic Forces

a)Central Forces

b)Angular Forces

4.2 Bulk Modes. ,

4.3 Surface Modes N

4.3.1 Semi-Infinite Linear Chain

a)Mo=M

b)Bo=B

4.3.2 Semi-Infinite Crystals

a)The Slab Method . N . N

b)Exact Method for the Calculation of Surface Modes

c)Relaxation and Reconstruction of Surfaces from Phonon Calculations

d)Experimental Determination of Surface Modes

4.3.3 Brief Remarks on Adsorbed Layers

4.4 Spectral Densities of Modes

4.5 Vibrational Thermodynamical Functions

4,5.1 Surface Vibrational Entropy ,

4.5.2 Surface Internal Energy ,

4.5.3 Surface Specific Heat at Constant Volume,

4.6 Mean Square Displacements

4.6.1 Theory

4.6.2 Experimental Techniques

a)Diffraction Experiments

b)PhD and SEXAFS Experiments

c)Conclusion

Problems

5. Electronic Structure of Surfaces

5.1 Jellium Model

5.1.1 The Free Electron Gas Bounded by Infinite Barriers

a)One-dimensional Electron Gas

b)Three-dimensional Electron Gas

……

6.Adsorption Phenomena

Appendices

References

Subject Index

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