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内容推荐 本书通过阐述表面等离激元基本原理和光催化理论模型,结合经典研究案例展示,深入浅出地介绍了等离激元光催化的原理、应用及发展前景。首先从电磁场基本原理出发,简要介绍了材料的电磁性质、表面等离激元、等离激元弛豫等背景知识,其中重点介绍了等离激元近场增强、热电子和热效应诱导光催化原理和模型。其次从实验测量和理论计算出发,展示了等离激元光催化在分子和材料等领域的应用,主要围绕表面分子反应、水解离及相变、微纳材料生长三个方面的应用展开。本书将深化读者对近场光与纳米物质相互作用的理解,拓展纳米光子学原理及应用方面的认识。 本书适用于有光学相关研究经历的研究生和科研工作者,以及有电磁理论基础的物理学本科生,可作为物理、材料及化学等学科的研究生公共课程,以及光学和光学工程等学科的专业课程教材。 目录 Chapter 1 Introduction References Chapter 2 Electromagnetic Properties of Materials 2.1 Electromagnetic properties of the materials 2.2 Electromagnetic wave propagation 2.3 The dielectric function of Drude model 2.4 Dielectric function of Drude-Lorentz model References Chapter 3 Fundamentals of Surface Plasmons 3.1 Surface plasmon polaritons 3.1.1 Properties of surface plasmon polaritons 3.1.2 Excitation of surface plasmon polaritons 3.2 Localized surface plasmons References Chapter 4 Surface Plasmon Relaxation Effects 4.1 Energy distribution of free electrons 4.1.1 Sommerfeld free-electron model 4.1.2 The momentum and energy of free electrons in metal materials 4.1.3 The statistical distribution of free electrons in metallic materials 4.2 Plasmon-induced hot electrons 4.3 Thermal effect of surface plasmons References Chapter 5 Principles of Plasmon-Driven Photocatalysis 5.1 Local field-effect-driven photocatalysis 5.2 Hot-electron-driven photocatalysis 5.2.1 Indirect electron transfer 5.2.2 Direct electron transfer 5.3 Plasmon-exciton co-driven photocatalysis 5.4 Thermal-effect-driven photocatalysis References Chapter 6 Measurement and Analysis of Plasmon-Driven Photocatalysis 6.1 Design of surface plasmon structures 6.2 Measurement by chromatography and electron microscopy 6.3 Analytical methods for Raman spectra 6.4 Analytical methods of surface-plasmon-enhanced spectra References Chapter 7 Plasmon-Driven Catalysis of Molecular Reactions 7.1 Gas dissociation catalytic reactions 7.2 Surface molecular catalytic reactions 7.3 Single-molecule catalytic reactions References Chapter 8 Water Decomposition and Phase Transition of Plasmon-Driven Photocatalysis 8.1 Water splitting 8.2 Seawater desalination 8.3 Steam sterilization References Chapter 9 Plasmon-Driven Catalysis of Material Growth 9.1 Growth of metal structures 9.2 Growth of polymers 9.3 Growth of crystal References Acknowledgements |