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电子书 化工热力学(英文版高等教育双语教学推荐教材)
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作者
出版社 化学工业出版社
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介绍
内容推荐
本书应国内高校化工热力学课程双语教学的需要,吸取国内外最新教材的精华,参考国内多数高校执行的48学时安排与双语教学的需要与特点,精选教学内容,采用英文编写。
本书讲述并应用热力学基本原理,阐述流体的热力学性质及相平衡,对化工过程进行节能分析。原理阐述简练,例题与习题适量,注重利用热力学原理解决实际化工生产问题。
全书共分九章,主要内容有:导论,流体的pV-T关系,流体的热力学性质,混合物的热力学性质,溶液的热力学性质,流体相平衡,流动、压缩及膨胀过程热力学计算,蒸汽动力循环及制冷循环,化工过程的热力学分析。书中各章都配有例题及一定量的习题。习题设置注意知识点覆盖,并附有答案。
本书可作为高等学校化工类专业本科生的双语教学教科书与教学参考书。
目录
Chapter 1 Introduction
1.1 The Scope of Chemical Engineering Thermodynamics
1.2 System and Surroundings
1.3 The Chemical State and Fluid Properties
1.4 The First Law of Thermodynamics
1.4.1 The first law of thermodynamics for controlled mass system
1.4.2 The first law of thermodynamics for controlled volume system
1.5 The Second Law of Thermodynamics
1.5.1 The upper limit for the conversion of heat into work
1.5.2 Entropy
1.5.3 Mathematical statement of the second law
Problems
Chapter 2 Volumetric Properties of Fluids
2.1 p.V.T Behavior of Pure Substances
2.2 The Equations of State(EOS)of Fluid
2.2.1 The EOS of ideal gas
2.2.2 Virial equations of state
2.3 Cubic Equations of State
2.3.1 The van der Waals equation of state
2.3.2 The Redlich.Kwong(R.K)equation of state
2.3.3 The Soave.Redlich.Kwong(SRK)equation of state
2.3.4 The Peng.Robinson(P.R)equation of state
2.3.5 A generic cubic equation of state
2.4 Generalized Correlations of Gases
2.4.1 Theorem of corresponding states
2.4.2 Generalized cubic EOS
2.4.3 Two.parameter theorem of corresponding states
2.4.4 Three.parameter theorem of corresponding states
2.4.5 Generalized correlations of the second virial coefficient
2.5 Liquid & Liquid.like Roots of the Generic Cubic EOS
2.6 Generalized Correlations for Liquids
Problems
Chapter 3 Thermodynamic Properties of Fluids
3.1 Property Relations for Homogenous Phases
3.2 Calculations of Enthalpy and Entropy
3.3 Residual Properties
3.4 Residual Properties by EOS
3.5 Calculations of Liquid Enthalpy and Entropy
3.6 Generalized Property Correlations for Gases
3.6.1 Generalized compressibility factor Z for residual enthalpy and residual entropy
3.6.2 Generalized second virial coefficient for residual enthalpy and residual entropy
3.7 Thermodynamic Diagrams
3.8 Tables of Thermodynamic Properties
3.9 T.S Diagrams
3.9.1 Heating and cooling processes at isopiestic pressure
3.9.2 Throttling expansion processes
3.9.3 Isentropic expansion or compression processes
3.10 p.H Diagrams
3.11 H.S Diagrams
Problems
Chapter 4 Thermodynamic Properties of Mixtures
4.1 The Mixing Rules
4.2 The Calculations of Vm,mix and Zmix
4.2.1 Amagat’s law(part volume law)combined with Z graphs
4.2.2 EOS for a mixture of real gases
4.3 The Calculations of HR and SR
4.3.1 The calculations of HR and SR by EOS
4.3.2 The calculations of HR and SR by generalized correlation graphs
Problems
Chapter 5 Solution Thermodynamics
5.1 Property Relations for Open Systems and Chemical Potential
5.2 Partial Properties
5.3 Fugacity and Fugacity Coefficient
5.3.1 Fugacity calculations for pure gases
5.3.2 Fugacity calculations for pure liquids
5.3.3 Fugacity calculations for species in solution
5.3.4 Application of Microsoft Excel in the thermodynamic property calculations
5.4 The Ideal Solution and Standard State
5.5 Excess Properties and Property Change in Mixing
5.5.1 Excess properties
5.5.2 Property change in mixing
5.5.3 H.x graph
5.6 Activity and Activity Coefficient
5.6.1 The Wohl type equations
5.6.2 The gamma equation based on local composition
5.6.3 The UNIQUAC and UNIFAC model
Problems
Chapter 6 Phase Equilibrium
6.1 The Criterion of Phases Equilibrium
6.2 Vapor.Liquid Equilibrium
6.2.1 VLE under low pressures
6.2.2 VLE under moderate pressures
6.2.3 VLE under high pressures
6.3 Gas.Liquid Equilibrium
6.4 Liquid.Liquid Equilibrium
6.4.1 LLE phase diagrams
6.4.2 The stability of liquid solution
6.4.3 LLE calculations
6.5 Vapor.Liquid.Liquid Equilibrium (VLLE)
Problems
Chapter 7 Thermodynamics of Flow Process
7.1 Conservation of Mass
7.2 Conservat
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